Asyraf, M. R. M. et al. in Advanced Composites in Aerospace Engineering Applications (eds Mazlan, N. et al.) 471–498 (Springer, 2022).
Liu, Y. et al. Biomimetic electroactive materials and devices for regenerative engineering. Nat. Rev. Electr. Eng. 2, 188–204 (2025).
Naguib, M., Mochalin, V. N., Barsoum, M. W. & Gogotsi, Y. 25th anniversary article: MXenes: a new family of two-dimensional materials. Adv. Mater. 26, 992–1005 (2014).
Naguib, M. et al. Two-dimensional nanocrystals produced by exfoliation of Ti3AlC2. Adv. Mater. 23, 4248–4253 (2011).
Lipatov, A. et al. High electrical conductivity and breakdown current density of individual monolayer Ti3C2Tx MXene flakes. Matter 4, 1413–1427 (2021).
Lipatov, A. et al. Elastic properties of 2D Ti3C2Tx MXene monolayers and bilayers. Sci. Adv. 4, eaat0491 (2018).
Li, X. et al. MXene chemistry, electrochemistry and energy storage applications. Nat. Rev. Chem. 6, 389–404 (2022).
Gogotsi, Y. & Huang, Q. MXenes: two-dimensional building blocks for future materials and devices. ACS Nano 15, 5775–5780 (2021).
Anasori, B., Lukatskaya, M. R. & Gogotsi, Y. 2D metal carbides and nitrides (MXenes) for energy storage. Nat. Rev. Mater. 2, 16098 (2017).
Simon, P. & Gogotsi, Y. Perspectives for electrochemical capacitors and related devices. Nat. Mater. 19, 1151–1163 (2020).
Ding, L. et al. MXene molecular sieving membranes for highly efficient gas separation. Nat. Commun. 9, 155 (2018).
VahidMohammadi, A., Rosen, J. & Gogotsi, Y. The world of two-dimensional carbides and nitrides (MXenes). Science 372, eabf1581 (2021).
Shahzad, F. et al. Electromagnetic interference shielding with 2D transition metal carbides (MXenes). Science 353, 1137–1140 (2016).
Iqbal, A. et al. Anomalous absorption of electromagnetic waves by 2D transition metal carbonitride Ti3CNTx (MXene). Science 369, 446–450 (2020).
Han, M. et al. Electrochemically modulated interaction of MXenes with microwaves. Nat. Nanotechnol. 18, 373–379 (2023).
Yang, M. & Kotov, N. A. Quantitative biomimetics of high-performance materials. Nat. Rev. Mater. 10, 382–395 (2025).
Wegst, U. G. K., Bai, H., Saiz, E., Tomsia, A. P. & Ritchie, R. O. Bioinspired structural materials. Nat. Mater. 14, 23–36 (2015).
Barthelat, F., Yin, Z. & Buehler, M. J. Structure and mechanics of interfaces in biological materials. Nat. Rev. Mater. 1, 16007 (2016).
Anasori, B. & Gogotsi, Y. 2D Metal Carbides and Nitrides (MXenes): Structure, Properties and Applications (Springer, 2019).
Xu, B. & Gogotsi, Y. MXenes — the fastest growing materials family in the two-dimensional world. Chin. Chem. Lett. 31, 919–921 (2020).
Gogotsi, Y. & Anasori, B. The rise of MXenes. ACS Nano 13, 8491–8494 (2019).
Lim, K. R. G. et al. Fundamentals of MXene synthesis. Nat. Synth. 1, 601–614 (2022).
Alhabeb, M. et al. Guidelines for synthesis and processing of two-dimensional titanium carbide (Ti3C2Tx MXene). Chem. Mater. 29, 7633–7644 (2017).
Sun, Z., Music, D., Ahuja, R., Li, S. & Schneider, J. M. Bonding and classification of nanolayered ternary carbides. Phys. Rev. B 70, 092102 (2004).
Barsoum, M. W. MAX Phases: Properties of Machinable Ternary Carbides and Nitrides (Wiley, 2013).
Ghidiu, M., Lukatskaya, M. R., Zhao, M.-Q., Gogotsi, Y. & Barsoum, M. W. Conductive two-dimensional titanium carbide ‘clay’ with high volumetric capacitance. Nature 516, 78–81 (2014).
Li, M. et al. Element replacement approach by reaction with Lewis acidic molten salts to synthesize nanolaminated MAX phases and MXenes. J. Am. Chem. Soc. 141, 4730–4737 (2019).
Sun, W. et al. Electrochemical etching of Ti2AlC to Ti2CTx (MXene) in low-concentration hydrochloric acid solution. J. Mater. Chem. A 5, 21663–21668 (2017).
Yang, S. et al. Fluoride-free synthesis of two-dimensional titanium carbide (MXene) using a binary aqueous system. Angew. Chem. Int. Ed. 130, 15717–15721 (2018).
Naguib, M. et al. New two-dimensional niobium and vanadium carbides as promising materials for Li-ion batteries. J. Am. Chem. Soc. 135, 15966–15969 (2013).
Anasori, B. et al. Two-dimensional, ordered, double transition metals carbides (MXenes). ACS Nano 9, 9507–9516 (2015).
Naguib, M. et al. Two-dimensional transition metal carbides. ACS Nano 6, 1322–1331 (2012).
Wei, Y., Zhang, P., Soomro, R. A., Zhu, Q. & Xu, B. Advances in the synthesis of 2D MXenes. Adv. Mater. 33, 2103148 (2021).
Sang, X. et al. Atomic defects in monolayer titanium carbide (Ti3C2Tx) MXene. ACS Nano 10, 9193–9200 (2016).
Li, Y. et al. A general Lewis acidic etching route for preparing MXenes with enhanced electrochemical performance in non-aqueous electrolyte. Nat. Mater. 19, 894–899 (2020).
Urbankowski, P. et al. Synthesis of two-dimensional titanium nitride Ti4N3 (MXene). Nanoscale 8, 11385–11391 (2016).
Kamysbayev, V. et al. Covalent surface modifications and superconductivity of two-dimensional metal carbide MXenes. Science 369, 979–983 (2020).
Liu, L. et al. Exfoliation and delamination of Ti3C2Tx MXene prepared via molten salt etching route. ACS Nano 16, 111–118 (2022).
Arole, K. et al. Water-dispersible Ti3C2Tz MXene nanosheets by molten salt etching. iScience 24, 103403 (2021).
Wang, Y. et al. Ultrafast synthesis of MXenes in minutes via low-temperature molten salt etching. Adv. Mater. 36, 2410736 (2024).
Cao, W.-T. et al. Binary strengthening and toughening of MXene/cellulose nanofiber composite paper with nacre-inspired structure and superior electromagnetic interference shielding properties. ACS Nano 12, 4583–4593 (2018).
Ling, Z. et al. Flexible and conductive MXene films and nanocomposites with high capacitance. Proc. Natl Acad. Sci. USA 111, 16676–16681 (2014).
Wang, L., Zhang, M., Yang, B. & Tan, J. Lightweight, robust, conductive composite fibers based on MXene@aramid nanofibers as sensors for smart fabrics. ACS Appl. Mater. Interfaces 13, 41933–41945 (2021).
Zhang, J. et al. Scalable manufacturing of free-standing, strong Ti3C2Tx MXene films with outstanding conductivity. Adv. Mater. 32, 2001093 (2020).
Eda, G., Fanchini, G. & Chhowalla, M. Large-area ultrathin films of reduced graphene oxide as a transparent and flexible electronic material. Nat. Nanotechnol. 3, 270–274 (2008).
Stankovich, S. et al. Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide. Carbon 45, 1558–1565 (2007).
Stankovich, S. et al. Graphene-based composite materials. Nature 442, 282–286 (2006).
Becerril, H. A. et al. Evaluation of solution-processed reduced graphene oxide films as transparent conductors. ACS Nano 2, 463–470 (2008).
Naguib, M. et al. MXene: a promising transition metal carbide anode for lithium-ion batteries. Electrochem. Commun. 16, 61–64 (2012).
Rakhi, R. B., Ahmed, B., Hedhili, M. N., Anjum, D. H. & Alshareef, H. N. Effect of postetch annealing gas composition on the structural and electrochemical properties of Ti2CTx MXene electrodes for supercapacitor applications. Chem. Mater. 27, 5314–5323 (2015).
Zhang, C. J. et al. Oxidation stability of colloidal two-dimensional titanium carbides (MXenes). Chem. Mater. 29, 4848–4856 (2017).
Wu, M. et al. V2CTx and Ti3C2Tx MXenes nanosheets for gas sensing. ACS Appl. Nano Mater. 4, 6257–6268 (2021).
Hantanasirisakul, K. & Gogotsi, Y. Electronic and optical properties of 2D transition metal carbides and nitrides (MXenes). Adv. Mater. 30, 1804779 (2018).
Halim, J. et al. Synthesis and characterization of 2D molybdenum carbide (MXene). Adv. Funct. Mater. 26, 3118–3127 (2016).
Anasori, B. et al. Control of electronic properties of 2D carbides (MXenes) by manipulating their transition metal layers. Nanoscale Horiz. 1, 227–234 (2016).
Hart, J. L. et al. Control of MXenes’ electronic properties through termination and intercalation. Nat. Commun. 10, 522 (2019).
Tang, Q., Zhou, Z. & Shen, P. Are MXenes promising anode materials for Li ion batteries? Computational studies on electronic properties and Li storage capability of Ti3C2 and Ti3C2X2 (X = F, OH) monolayer. J. Am. Chem. Soc. 134, 16909–16916 (2012).
Xie, Y. & Kent, P. R. C. Hybrid density functional study of structural and electronic properties of functionalized Tin+1Xn (X = C, N) monolayers. Phys. Rev. B 87, 235441 (2013).
Zhang, J. et al. Additive-free MXene liquid crystals and fibers. ACS Cent. Sci. 6, 254–265 (2020).
Rong, C. et al. Elastic properties and tensile strength of 2D Ti3C2Tx MXene monolayers. Nat. Commun. 15, 1566 (2024).
Mauchamp, V. et al. Enhanced and tunable surface plasmons in two-dimensional Ti3C2 stacks: electronic structure versus boundary effects. Phys. Rev. B 89, 235428 (2014).
Li, R., Zhang, L., Shi, L. & Wang, P. MXene Ti3C2: an effective 2D light-to-heat conversion material. ACS Nano 11, 3752–3759 (2017).
Li, Y., Lian, W. & Cheng, Q. High-performance nacre-inspired 2D carbon-based nanocomposites. Adv. Mater. 37, 2501932 (2025).
Wang, H. et al. Tough and conductive nacre-inspired MXene/epoxy layered bulk nanocomposites. Angew. Chem. Int. Ed. 62, e202216874 (2023).
Gao, H., Ji, B., Jäger, I. L., Arzt, E. & Fratzl, P. Materials become insensitive to flaws at nanoscale: lessons from nature. Proc. Natl Acad. Sci. USA 100, 5597–5600 (2003).
Suzuki, M. et al. An acidic matrix protein, Pif, is a key macromolecule for nacre formation. Science 325, 1388–1390 (2009).
Cartwright, J. H. E. & Checa, A. G. The dynamics of nacre self-assembly. J. R. Soc. Interface 4, 491–504 (2007).
Mishra, N. & Kandasubramanian, B. Biomimetic design of artificial materials inspired by iridescent nacre structure and its growth mechanism. Polym. Plast. Technol. Eng. 57, 1592–1606 (2018).
Shao, Y., Zhao, H.-P., Feng, X.-Q. & Gao, H. Discontinuous crack-bridging model for fracture toughness analysis of nacre. J. Mech. Phys. Solids 60, 1400–1419 (2012).
Kakisawa, H. & Sumitomo, T. The toughening mechanism of nacre and structural materials inspired by nacre. Sci. Technol. Adv. Mater. 12, 064710 (2012).
Wang, R. Z., Suo, Z., Evans, A. G., Yao, N. & Aksay, I. A. Deformation mechanisms in nacre. J. Mater. Res. 16, 2485–2493 (2001).
Maghsoudi-Ganjeh, M., Lin, L., Yang, X. & Zeng, X. Computational modeling and simulation of bioinspired nacre-like composites. J. Mater. Res. 36, 2651–2661 (2021).
Espinosa, H. D., Rim, J. E., Barthelat, F. & Buehler, M. J. Merger of structure and material in nacre and bone — perspectives on de novo biomimetic materials. Prog. Mater. Sci. 54, 1059–1100 (2009).
Gao, H. Application of fracture mechanics concepts to hierarchical biomechanics of bone and bone-like materials. Int. J. Fract. 138, 101–137 (2006).
Yeom, B. et al. Abiotic tooth enamel. Nature 543, 95–98 (2017).
Munch, E. et al. Tough, bio-inspired hybrid materials. Science 322, 1516–1520 (2008).
Abdolhosseinzadeh, S., Jiang, X., Zhang, H., Qiu, J. & Zhang, C.(J.) Perspectives on solution processing of two-dimensional MXenes. Mater. Today 48, 214–240 (2021).
White, K. E. et al. Atomic-scale investigations of Ti3C2Tx MXene surfaces. Matter 7, 2609–2618 (2024).
Wan, S. et al. Scalable ultrastrong MXene films with superior osteogenesis. Nature 634, 1103–1110 (2024).
Zhang, Y. et al. Mussel-inspired self-healing adhesive MXene hydrogel for epidermal electronics. Device 2, 100253 (2024).
Yoon, Y. H. et al. Mussel-inspired self-assembly of PtO4 atomic catalysts for interfacial synergistic hydrogen evolution. Adv. Sci. 12, e07807 (2025).
Cheng, H. et al. One single graphene oxide film for responsive actuation. ACS Nano 10, 9529–9535 (2016).
Cerda, E. & Mahadevan, L. Geometry and physics of wrinkling. Phys. Rev. Lett. 90, 074302 (2003).
Tan, Y., Hu, B., Song, J., Chu, Z. & Wu, W. Bioinspired multiscale wrinkling patterns on curved substrates: an overview. Nanomicro Lett. 12, 101 (2020).
Yaron, D. J. & Kowalewski, T. Beware the nanovoids. Nat. Mater. 18, 1154–1155 (2019).
Li, Y. & Cheng, Q. Discovery and elimination strategies of voids in two-dimensional carbon nanocomposites. Acc. Mater. Res. 5, 358–370 (2024).
Vásárhelyi, L., Kónya, Z., Kukovecz, Á & Vajtai, R. Microcomputed tomography–based characterization of advanced materials: a review. Mater. Today Adv. 8, 100084 (2020).
Roldán, D., Redenbach, C., Schladitz, K., Klingele, M. & Godehardt, M. Reconstructing porous structures from FIB-SEM image data: optimizing sampling scheme and image processing. Ultramicroscopy 226, 113291 (2021).
Prieto, G. in Encyclopedia of Membranes (eds Drioli, E. & Giorno, L.) 1–3 (Springer, 2015).
Kampschulte, M. et al. Nano-computed tomography: technique and applications. RöFo 188, 146–154 (2016).
Haugen, H. J., Qasim, S. B., Matinlinna, J. P., Vallittu, P. & Nogueira, L. P. Nano-CT as tool for characterization of dental resin composites. Sci. Rep. 10, 15520 (2020).
Huang, C., Wan, S. & Cheng, Q. Bioinspired MXene-based nanocomposite fibers. 2D Mater. 12, 042004 (2025).
Wan, S. et al. Strong sequentially bridged MXene sheets. Proc. Natl Acad. Sci. USA 117, 27154–27161 (2020).
Cheng, Q., Duan, J., Zhang, Q. & Jiang, L. Learning from nature: constructing integrated graphene-based artificial nacre. ACS Nano 9, 2231–2234 (2015).
Mao, L. et al. Stiffening of graphene oxide films by soft porous sheets. Nat. Commun. 10, 3677 (2019).
Xin, G. et al. Highly thermally conductive and mechanically strong graphene fibers. Science 349, 1083–1087 (2015).
Zhang, Z., Zheng, L., Huang, W. & Cheng, Q. Improving strength and toughness of graphene film through metal ion bridging. Proc. Natl Acad. Sci. USA 121, e2322663121 (2024).
Lichtenegger, H. C., Schöberl, T., Bartl, M. H., Waite, H. & Stucky, G. D. High abrasion resistance with sparse mineralization: copper biomineral in worm jaws. Science 298, 389–392 (2002).
Lichtenegger, H. C. et al. Zinc and mechanical prowess in the jaws of Nereis, a marine worm. Proc. Natl Acad. Sci. USA 100, 9144–9149 (2003).
Harrington, M. J., Masic, A., Holten-Andersen, N., Waite, J. H. & Fratzl, P. Iron-clad fibers: a metal-based biological strategy for hard flexible coatings. Science 328, 216–220 (2010).
Meyers, M. A., McKittrick, J. & Chen, P.-Y. Structural biological materials: critical mechanics-materials connections. Science 339, 773–779 (2013).
Podsiadlo, P. et al. Ultrastrong and stiff layered polymer nanocomposites. Science 318, 80–83 (2007).
Wan, S. et al. Sequentially bridged graphene sheets with high strength, toughness, and electrical conductivity. Proc. Natl Acad. Sci. USA 115, 5359–5364 (2018).
Wan, S. et al. High-strength scalable MXene films through bridging-induced densification. Science 374, 96–99 (2021).
Low, J., Zhang, L., Tong, T., Shen, B. & Yu, J. TiO2/MXene Ti3C2 composite with excellent photocatalytic CO2 reduction activity. J. Catal. 361, 255–266 (2018).
Ali, A. et al. Effect of synthesis on performance of MXene/iron oxide anode material for lithium-ion batteries. Langmuir 34, 11325–11334 (2018).
Chen, S., Wang, H.-Z., Zhao, R.-Q., Rao, W. & Liu, J. Liquid metal composites. Matter 2, 1446–1480 (2020).
Yi, P. et al. MXene-reinforced liquid metal/polymer fibers via interface engineering for wearable multifunctional textiles. ACS Nano 16, 14490–14502 (2022).
Zhang, H. et al. An integrated self-healing anode assembled via dynamic encapsulation of liquid metal with a 3D Ti3C2Tx network for enhanced lithium storage. Energy Environ. Sci. 15, 5240–5250 (2022).
Li, X. et al. Inter-skeleton conductive routes tuning multifunctional conductive foam for electromagnetic interference shielding, sensing and thermal management. Nanomicro Lett. 17, 52 (2024).
Li, W. et al. Ultrastrong MXene film induced by sequential bridging with liquid metal. Science 385, 62–68 (2024).
Wang, Y. et al. Wet spun cellulose nanocrystal/MXene hybrid fiber regulated by bridging effect for high electrochemical performance supercapacitor. Adv. Compos. Hybrid Mater. 7, 120 (2024).
Liang, Q. et al. Interfacial modulation of Ti3C2Tx MXene by cellulose nanofibrils to construct hybrid fibers with high volumetric specific capacitance. Small 20, 2307344 (2024).
Usman, K. A. S. et al. Inducing liquid crystallinity in dilute MXene dispersions for facile processing of multifunctional fibers. J. Mater. Chem. A 10, 4770–4781 (2022).
Gao, X. et al. Maximizing ion accessibility in MXene-knotted carbon nanotube composite electrodes for high-rate electrochemical energy storage. Nat. Commun. 11, 6160 (2020).
Zhao, M.-Q. et al. Flexible MXene/carbon nanotube composite paper with high volumetric capacitance. Adv. Mater. 27, 339–345 (2015).
Zhao, X. et al. Carbon nanotubes boosts the toughness and conductivity of wet-spun MXene fibers for fiber-shaped super capacitors. Carbon 200, 38–46 (2022).
Liu, Y., Zou, W., Zhao, N. & Xu, J. Electrically insulating PBO/MXene film with superior thermal conductivity, mechanical properties, thermal stability, and flame retardancy. Nat. Commun. 14, 5342 (2023).
Zhao, C. et al. Layered nanocomposites by shear-flow-induced alignment of nanosheets. Nature 580, 210–215 (2020).
Xu, J. et al. Multi-scale ordering in highly stretchable polymer semiconducting films. Nat. Mater. 18, 594–601 (2019).
Zhou, T. et al. Large-area ultrastrong and stiff layered MXene nanocomposites by shear-flow-induced alignment of nanosheets. ACS Nano 16, 12013–12023 (2022).
Wan, S. et al. Synergistic Toughening of graphene oxide–molybdenum disulfide–thermoplastic polyurethane ternary artificial nacre. ACS Nano 9, 708–714 (2015).
Wan, S. et al. Fatigue resistant bioinspired composite from synergistic two-dimensional nanocomponents. ACS Nano 11, 7074–7083 (2017).
Zhou, T. et al. Ultratough graphene–black phosphorus films. Proc. Natl Acad. Sci. USA 117, 8727–8735 (2020).
Zhou, T. et al. Super-tough MXene-functionalized graphene sheets. Nat. Commun. 11, 2077 (2020).
Liu, Y. et al. Tailoring sample-wide pseudo-magnetic fields on a graphene–black phosphorus heterostructure. Nat. Nanotechnol. 13, 828–834 (2018).
Xia, F., Wang, H. & Jia, Y. Rediscovering black phosphorus as an anisotropic layered material for optoelectronics and electronics. Nat. Commun. 5, 4458 (2014).
Zhao, Y. et al. Surface coordination of black phosphorus for robust air and water stability. Angew. Chem. Int. Ed. 55, 5003–5007 (2016).
Cheng, Y., Yang, J., Kuang, X. & Cheng, Q. Effect of voids on the performance of MXene-based nanocomposites. Sci. China Mater. 68, 2230–2239 (2025).
Huang, H. & Talreja, R. Effects of void geometry on elastic properties of unidirectional fiber reinforced composites. Compos. Sci. Technol. 65, 1964–1981 (2005).
Mehdikhani, M., Gorbatikh, L., Verpoest, I. & Lomov, S. V. Voids in fiber-reinforced polymer composites: a review on their formation, characteristics, and effects on mechanical performance. J. Compos. Mater. 53, 1579–1669 (2019).
Wan, S. et al. Ultrastrong MXene films via the synergy of intercalating small flakes and interfacial bridging. Nat. Commun. 13, 7340 (2022).
Wan, S. et al. High-strength scalable graphene sheets by freezing stretch-induced alignment. Nat. Mater. 20, 624–631 (2021).
Zhang, X. et al. Carbon nanotube fibers with dynamic strength up to 14 GPa. Science 384, 1318–1323 (2024).
Sun, C. et al. Plasticization stretching strategy towards high strength nacre-like graphene-based composites. Compos. Commun. 27, 100815 (2021).
Shen, K. et al. Intercalated oligomer doubles plasticity for strong and conductive graphene papers and composites. Carbon 208, 160–169 (2023).
Yang, J. et al. Water-induced strong isotropic MXene-bridged graphene sheets for electrochemical energy storage. Science 383, 771–777 (2024).
Lukatskaya, M. R. et al. Ultra-high-rate pseudocapacitive energy storage in two-dimensional transition metal carbides. Nat. Energy 2, 17105 (2017).
Lin, Z. et al. Capacitance of Ti3C2Tx MXene in ionic liquid electrolyte. J. Power Sources 326, 575–579 (2016).
Lv, Z. et al. 2D biomimetic membranes constructed by charge assembly and hydrogen bonding for precise ion separation. Adv. Mater. 37, 2419496 (2025).
Yu, H. et al. Rearrangement of water molecules confined in 2D nanochannels regulates ion transport of membrane towards lithium extraction. Adv. Funct. Mater. 22, e20750 (2025).
Fleischmann, S. et al. Continuous transition from double-layer to Faradaic charge storage in confined electrolytes. Nat. Energy 7, 222–228 (2022).
Futamura, R. et al. Partial breaking of the Coulombic ordering of ionic liquids confined in carbon nanopores. Nat. Mater. 16, 1225–1232 (2017).
Bi, L. et al. MXene functionalized Kevlar yarn via automated, continuous dip coating. Adv. Funct. Mater. 34, 2312434 (2024).
Han, M. et al. Versatility of infrared properties of MXenes. Mater. Today 64, 31–39 (2023).
Zhao, H., Yang, Z. & Guo, L. Nacre-inspired composites with different macroscopic dimensions: strategies for improved mechanical performance and applications. NPG Asia Mater. 10, 1–22 (2018).
Eom, W. et al. Large-scale wet-spinning of highly electroconductive MXene fibers. Nat. Commun. 11, 2825 (2020).
Laperrousaz, S. et al. Electronic fibres via the thermal drawing of liquid-metal-embedded elastomers. Nat. Electron. 8, 1072–1081 (2025).
Zhou, T. et al. Ultra-compact MXene fibers by continuous and controllable synergy of interfacial interactions and thermal drawing-induced stresses. Nat. Commun. 13, 4564 (2022).
Zhou, T. et al. Interlocking-governed ultra-strong and highly conductive MXene fibers through fluidics-assisted thermal drawing. Adv. Mater. 35, 2305807 (2023).
Lee, Y. et al. Scalable production of tailor-designed MXene−hydrogel core−shell fibers via dual stress-guided alignment during thermal drawing. ACS Nano 20, 731–743 (2026).
Liu, Y., Wu, Y. & Wang, X. Thermal transports in the MXenes family: opportunities and challenges. Nano Res. 17, 7700–7716 (2024).
Zhang, B. et al. Transforming Ti3C2Tx MXene’s intrinsic hydrophilicity into superhydrophobicity for efficient photothermal membrane desalination. Nat. Commun. 13, 3315 (2022).
Zhou, P. et al. Recent advances in MXene-based membrane for solar-driven interfacial evaporation desalination. Chem. Eng. J. 464, 142508 (2023).
Liu, L.-X. et al. Tough and electrically conductive Ti3C2Tx MXene-based core–shell fibers for high-performance electromagnetic interference shielding and heating application. Chem. Eng. J. 430, 133074 (2022).
Liu, X. et al. Air-permeable, multifunctional, dual-energy-driven MXene-decorated polymeric textile-based wearable heaters with exceptional electrothermal and photothermal conversion performance. J. Mater. Chem. A 8, 12526–12537 (2020).
Yang, P. et al. Realization of 3D epoxy resin/Ti3C2Tx MXene aerogel composites for low-voltage electrothermal heating. 2D Mater. 8, 025022 (2021).
Wang, J., Shen, M., Liu, Z. & Wang, W. MXene materials for advanced thermal management and thermal energy utilization. Nano Energy 97, 107177 (2022).
Li, K. et al. Stepless IR chromism in Ti3C2Tx MXene tuned by interlayer water molecules. Adv. Mater. 36, 2308189 (2024).
Li, X., Li, M., Li, X., Fan, X. & Zhi, C. Low infrared emissivity and strong stealth of Ti-based MXenes. Research 2022, 9892628 (2022).
Li, Y. et al. 2D Ti3C2Tx MXenes: visible black but infrared white materials. Adv. Mater. 33, 2103054 (2021).
Hassan, T. et al. Multifunctional MXene/carbon nanotube Janus film for electromagnetic shielding and infrared shielding/detection in harsh environments. Nanomicro Lett. 16, 216 (2024).
Lei, L. et al. Wettability gradient-induced diode: MXene-engineered membrane for passive-evaporative cooling. Nanomicro Lett. 16, 159 (2024).
Kang, G. et al. Electromagnetic interference shielding using metal and MXene thin films. Nature 647, 356–363 (2025).
Han, M. et al. Beyond Ti3C2Tx: MXenes for electromagnetic interference shielding. ACS Nano 14, 5008–5016 (2020).
Iqbal, A., Hassan, T., Naqvi, S. M., Gogotsi, Y. & Koo, C. M. MXenes for multispectral electromagnetic shielding. Nat. Rev. Electr. Eng. 1, 180–198 (2024).
Ott, H. W. Electromagnetic Compatibility Engineering (Wiley, 2009).
Iqbal, A., Sambyal, P. & Koo, C. M. 2D MXenes for electromagnetic shielding: a review. Adv. Funct. Mater. 30, 2000883 (2020).
He, P., Cao, M. S., Cao, W. Q. & Yuan, J. Developing MXenes from wireless communication to electromagnetic attenuation. Nanomicro Lett. 13, 115 (2021).
Hareesh, M. S., Joseph, P. & George, S. Electromagnetic interference shielding: a comprehensive review of materials, mechanisms, and applications. Nanoscale Adv. 7, 4510–4534 (2025.
Lee, G. S. et al. Maximized internal scattering in heterostack Ti3C2Tx MXene/graphene oxide film for effective electromagnetic interference shielding. 2D Mater. 10, 035022 (2023).
Ren, Y. et al. Barrier membranes for guided bone regeneration (GBR): a focus on recent advances in collagen membranes. Int. J. Mol. Sci. 23, 14987 (2022).
Huang, Y. et al. Biodegradable microspheres made of conductive polyorganophosphazene showing antioxidant capacity for improved bone regeneration. Chem. Eng. J. 397, 125352 (2020).
Ma, J., Zhang, L. & Lei, B. Multifunctional MXene-based bioactive materials for integrated regeneration therapy. ACS Nano 17, 19526–19549 (2023).
Ou, L. et al. Graphene-based material-mediated immunomodulation in tissue engineering and regeneration: mechanism and significance. ACS Nano 17, 18669–18687 (2023).
Chen, Y. et al. Superior synergistic osteogenesis of MXene-based hydrogel through supersensitive drug release at mild heat. Adv. Funct. Mater. 34, 2309191 (2024).
Ou, Z. et al. Biodegradable Janus sonozyme with continuous reactive oxygen species regulation for treating infected critical-sized bone defects. Nat. Commun. 15, 10525 (2024).
Wang, T. et al. Bioinspired artificial antioxidases for efficient redox homeostasis and maxillofacial bone regeneration. Nat. Commun. 16, 856 (2025).
Asadi Tokmedash, M. & Min, J. Designer micro-/nanocrumpled MXene multilayer coatings accelerate osteogenesis and regulate macrophage polarization. ACS Appl. Mater. Interfaces 16, 21415–21426 (2024).
Song, Q. et al. Multifunctional hydrogel with synergistic reactive oxygen species scavenging and macrophage polarization-induced osteo-immunomodulation for enhanced bone regeneration. ACS Appl. Mater. Interfaces 17, 38985–39001 (2025).
Zhang, J., Tang, S., Ding, N., Ma, P. & Zhang, Z. Surface-modified Ti3C2 MXene nanosheets for mesenchymal stem cell osteogenic differentiation via photothermal conversion. Nanoscale Adv. 5, 2921–2932 (2023).
Mirvakili, S. M. & Hunter, I. W. Artificial muscles: mechanisms, applications, and challenges. Adv. Mater. 30, 1704407 (2018).
Haines, C. S. et al. New twist on artificial muscles. Proc. Natl Acad. Sci. USA 113, 11709–11716 (2016).
Mirfakhrai, T., Madden, J. D. W. & Baughman, R. H. Polymer artificial muscles. Mater. Today 10, 30–38 (2007).
Lee, G. S. et al. 2D materials beyond post-AI era: smart fibers, soft robotics, and single atom catalysts. Adv. Mater. 36, 2307689 (2024).
Kim, I. H. et al. Human-muscle-inspired single fibre actuator with reversible percolation. Nat. Nanotechnol. 17, 1198–1205 (2022).
Xin, G. et al. Microfluidics-enabled orientation and microstructure control of macroscopic graphene fibres. Nat. Nanotechnol. 14, 168–175 (2019).
Fu, J. et al. Large stroke radially oriented MXene composite fiber tensile artificial muscles. Sci. Adv. 11, eadt1560 (2025).
Shin, H., Jeong, W. & Han, T. H. Maximizing light-to-heat conversion of Ti3C2Tx MXene metamaterials with wrinkled surfaces for artificial actuators. Nat. Commun. 15, 10507 (2024).
Shi, M. & Yeatman, E. M. A comparative review of artificial muscles for microsystem applications. Microsyst. Nanoeng. 7, 95 (2021).
Leng, X. et al. Recent advances in twisted-fiber artificial muscles. Adv. Intell. Syst. 3, 2000185 (2021).
Lima, M. D. et al. Electrically, chemically, and photonically powered torsional and tensile actuation of hybrid carbon nanotube yarn muscles. Science 338, 928–932 (2012).
Foroughi, J. et al. Torsional carbon nanotube artificial muscles. Science 334, 494–497 (2011).
Wang, L. et al. Integrated thermal management-sensing-actuation functional artificial muscles. Mater. Horiz. 12, 1262–1273 (2025).
Kanik, M. et al. Strain-programmable fiber-based artificial muscle. Science 365, 145–150 (2019).
Jäger, I. & Fratzl, P. Mineralized collagen fibrils: a mechanical model with a staggered arrangement of mineral particles. Biophys. J. 79, 1737–1746 (2000).
Cai, G., Ciou, J.-H., Liu, Y., Jiang, Y. & Lee, P. S. Leaf-inspired multiresponsive MXene-based actuator for programmable smart devices. Sci. Adv. 5, eaaw7956 (2019).
Zeng, J. et al. DeePMD-kit v3: a multiple-backend framework for machine learning potentials. J. Chem. Theory Comput. 21, 4375–4385 (2025).
Zeng, J., Cao, L. & Zhu, T. in Quantum Chemistry in the Age of Machine Learning (ed. Dral, P. O.) 279–294 (Elsevier, 2023).
Kapil, V. et al. The first-principles phase diagram of monolayer nanoconfined water. Nature 609, 512–516 (2022).
Hou, P. et al. Unraveling the oxidation behaviors of MXenes in aqueous systems by active-learning-potential molecular-dynamics simulation. Angew. Chem. Int. Ed. 62, e202304205 (2023).
Tian, Y. et al. Theoretical insights on potential-dependent oxidation behaviors and antioxidant strategies of MXenes. Nat. Commun. 15, 10099 (2024).
Hou, P. et al. Proton-driven dynamic behavior of nanoconfined water in hydrophilic MXene sheets. Angew. Chem. Int. Ed. 63, e202411849 (2024).
Hedman, D. et al. Dynamics of growing carbon nanotube interfaces probed by machine learning-enabled molecular simulations. Nat. Commun. 15, 4076 (2024).
Björk, J., Zhou, J., Persson, P. O. Å & Rosen, J. Two-dimensional materials by large-scale computations and chemical exfoliation of layered solids. Science 383, 1210–1215 (2024).
Chen, T. et al. Machine intelligence-accelerated discovery of all-natural plastic substitutes. Nat. Nanotechnol. 19, 782–791 (2024).
Shrestha, S. et al. Machine intelligence accelerated design of conductive MXene aerogels with programmable properties. Nat. Commun. 15, 4685 (2024).
Cao, W.-T. et al. MXene-reinforced cellulose nanofibril inks for 3D-printed smart fibres and textiles. Adv. Funct. Mater. 29, 1905898 (2019).
Cheng, B. & Wu, P. Scalable fabrication of Kevlar/Ti3C2Tx MXene intelligent wearable fabrics with multiple sensory capabilities. ACS Nano 15, 8676–8685 (2021).
Zhang, J. et al. Highly conductive Ti3C2Tx MXene hybrid fibers for flexible and elastic fiber-shaped supercapacitors. Small 15, 1804732 (2019).
Seyedin, S. et al. MXene composite and coaxial fibers with high stretchability and conductivity for wearable strain sensing textiles. Adv. Funct. Mater. 30, 1910504 (2020).
Yu, Y. et al. Highly tough and conductive silk fibroin/MXene composite fibers for electromagnetic interference shielding and motion sensing. Chem. Eng. J. 513, 162701 (2025).
Wei, S. et al. 3D cellulose network confining MXene/MnO2 enables flexible wet spinning microfibers for high-performance fiber-shaped Zn-ion capacitors. Int. J. Biol. Macromol. 276, 134152 (2024).
Ma, M. et al. Construction of gradient conductivity cellulose nanofiber/MXene composites with efficient electromagnetic interference shielding and excellent mechanical properties. Compos. Sci. Technol. 226, 109540 (2022).
Sun, Y. et al. MXene-xanthan nanocomposite films with layered microstructure for electromagnetic interference shielding and Joule heating. Chem. Eng. J. 410, 128348 (2021).
Liu, H. et al. Facile fabrication of flexible and ultrathin self-assembled Ti3C2Tx/bacterial cellulose composite films with multifunctional electromagnetic shielding and photothermal conversion performances. Chem. Eng. J. 454, 140288 (2023).
Wang, J., Ma, X., Zhou, J., Du, F. & Teng, C. Bioinspired, high-strength, and flexible MXene/aramid fiber for electromagnetic interference shielding papers with Joule heating performance. ACS Nano 16, 6700–6711 (2022).
Lee, G. S. et al. Mussel inspired highly aligned Ti3C2Tx MXene film with synergistic enhancement of mechanical strength and ambient stability. ACS Nano 14, 11722–11732 (2020).
Lipton, J. et al. Mechanically strong and electrically conductive multilayer MXene nanocomposites. Nanoscale 11, 20295–20300 (2019).
Zhan, Z., Song, Q., Zhou, Z. & Lu, C. Ultrastrong and conductive MXene/cellulose nanofiber films enhanced by hierarchical nano-architecture and interfacial interaction for flexible electromagnetic interference shielding. J. Mater. Chem. C 7, 9820–9829 (2019).
Weng, G.-M. et al. Layer-by-layer assembly of cross-functional semi-transparent MXene-carbon nanotubes composite films for next-generation electromagnetic interference shielding. Adv. Funct. Mater. 28, 1803360 (2018).
Zeng, Z. et al. Nanocellulose-MXene biomimetic aerogels with orientation-tunable electromagnetic interference shielding performance. Adv. Sci. 7, 2000979 (2020).
Wu, N. et al. Ultrathin cellulose nanofiber assisted ambient-pressure-dried, ultralight, mechanically robust, multifunctional MXene aerogels. Adv. Mater. 35, 2207969 (2023).
Wu, Z. et al. MXene/BC@CoFe2O4 aerogel with excellent electromagnetic interference shielding and enhanced mechanical property. J. Alloys Compd. 985, 174117 (2024).
Liu, H. et al. Mechanically robust and multifunctional Ti3C2Tx MXene composite aerogel for broadband EMI shielding. Carbon 221, 118948 (2024).
Chen, X., Yi, Y., Duan, R., Lu, C. & Zhou, Z. Dual cross-linked and vertically oriented MXene/polyvinyl alcohol aerogel for ultrabroadband electromagnetic interference shielding and thermal camouflage. Polymer 291, 126604 (2024).
Ji, X., Jiang, Y., Liu, T., Lin, S. & Du, A. MXene aerogel-based phase change film for synergistic thermal management inspired by antifreeze beetles. Cell Rep. Phys. Sci. 3, 100815 (2022).
Chen, J. et al. Polyvinyl alcohol–reinforced silk nanofiber/MXene composite aerogel as wearable sensors for detecting human motion. Surf. Interfaces 62, 106220 (2025).
Liu, R. et al. Well-cushioned and highly-elastic aerogel for multifunctional intelligent transportation packaging. Chem. Eng. J. 493, 152660 (2024).
Hou, M. et al. Mxene hybrid conductive hydrogels with mechanical flexibility, frost-resistance, photothermoelectric conversion characteristics and their multiple applications in sensing. Chem. Eng. J. 483, 149299 (2024).
Ni, Q.-Y. et al. Mechanical tough and stretchable quaternized cellulose nanofibrils/MXene conductive hydrogel for flexible strain sensor with multi-scale monitoring. J. Mater. Sci. Technol. 191, 181–191 (2024).
Yan, Q. et al. Bio-inspired stimuli-responsive Ti3C2Tx/PNIPAM anisotropic hydrogels for high-performance actuators. Adv. Funct. Mater. 33, 2301982 (2023).
Ge, G. et al. Ti3C2Tx MXene-activated fast gelation of stretchable and self-healing hydrogels: a molecular approach. ACS Nano 15, 2698–2706 (2021).
Huang, J., Huang, X. & Wu, P. Readily prepared and processed multifunctional MXene nanocomposite hydrogels for smart electronics. SmartMat 5, e1228 (2024).
Zheng, Y., Wang, Y., Zhao, J. & Li, Y. Electrostatic interfacial cross-linking and structurally oriented fiber constructed by surface-modified 2D MXene for high-performance flexible pseudocapacitive storage. ACS Nano 17, 2487–2496 (2023).
Liang, C. et al. Stiff and self-healing hydrogels by polymer entanglements in co-planar nanoconfinement. Nat. Mater. 24, 599–606 (2025).
Zhang, S. et al. High-strength, antiswelling directional layered PVA/MXene hydrogel for wearable devices and underwater sensing. Adv. Sci. 11, 2405880 (2024).
Geng, L. et al. Anisotropic double-network hydrogels integrated superior performance of strength, toughness and conductivity for flexible multi-functional sensors. Chem. Eng. J. 462, 142226 (2023).
Pi, M. et al. Rapid gelation of tough and anti-swelling hydrogels under mild conditions for underwater communication. Adv. Funct. Mater. 33, 2210188 (2023).
Ahmed, S., Li, B., Luo, S. & Liao, K. Heterogeneous Ti3C2Tx MXene-MWCNT@MoS2 film for enhanced long-term electromagnetic interference shielding in the moisture environment. ACS Appl. Mater. Interfaces 15, 49458–49467 (2023).
Xing, Y. et al. Multilayer ultrathin MXene@AgNW@MoS2 composite film for high-efficiency electromagnetic shielding. ACS Appl. Mater. Interfaces 15, 5787–5797 (2023).
Ma, Z. et al. Ultraflexible and mechanically strong double-layered aramid nanofiber–Ti3C2Tx MXene/silver nanowire nanocomposite papers for high-performance electromagnetic interference shielding. ACS Nano 14, 8368–8382 (2020).
Liu, R. et al. Ultrathin biomimetic polymeric Ti3C2Tx MXene composite films for electromagnetic interference shielding. ACS Appl. Mater. Interfaces 10, 44787–44795 (2018).
Pavlou, C. et al. Effective EMI shielding behaviour of thin graphene/PMMA nanolaminates in the THz range. Nat. Commun. 12, 4655 (2021).
Wang, Z. et al. Polarization manipulation of electromagnetic interference shielding effectiveness utilizing graphene film-based metamaterials. Nat. Commun. 17, 682 (2025).
Liang, C. et al. Superior electromagnetic interference shielding performances of epoxy composites by introducing highly aligned reduced graphene oxide films. Compos. Part A Appl. Sci. Manuf. 124, 105512 (2019).
Yang, Y., Wan, C., Huang, Q. & Hua, J. Pore-rich cellulose-derived carbon fiber@graphene core-shell composites for electromagnetic interference shielding. Nanomaterials 13, 174 (2023).
Zhang, Y. et al. Strong and conductive reduced graphene oxide-MXene porous films for efficient electromagnetic interference shielding. Nano Res. 15, 4916–4924 (2022).
Zheng, L. et al. Ultrastrong graphene films through confined assembly for extreme environmental applications. CCS Chem. 7, 3823–3835 (2025).
Luxa, J., Oliveira, F. M., Jellet, C. W., Gusmão, R. & Sofer, Z. Freestanding foils of NbSe2 and carbon nanotubes for efficient electromagnetic shielding. ACS Appl. Nano Mater. 6, 3333–3343 (2023).
Deng, F. et al. Regulating the electrical and mechanical properties of TaS2 films via van der Waals and electrostatic interaction for high performance electromagnetic interference shielding. Nanomicro Lett. 15, 106 (2023).
Wang, J. et al. MoS2 lubricate-toughened MXene/ANF composites for multifunctional electromagnetic interference shielding. Nanomicro Lett. 17, 36 (2024).
Islam, R., Mudila, H., Chahal, R., Ohlan, A. & Kumar, A. EMI shielding performance of PPy/Fe-WS2 nanocomposites in the Ku band. J. Mater. Chem. A 13, 14751–14764 (2025).
Wu, F., Xie, A., Sun, M., Jiang, W. & Zhang, K. Few-layer black phosphorus: a bright future in electromagnetic absorption. Mater. Lett. 193, 30–33 (2017).
Li, W., Yin, Z., Qi, L., Yu, B. & Xing, W. Scalable production of bioinspired MXene/black phosphorene nanocoatings for hydrophobic and fire-safe textiles with tunable electromagnetic interference and exceeding thermal management. Chem. Eng. J. 460, 141870 (2023).
Lin, H. et al. Harmonizing material quantity and terahertz wave interference shielding efficiency with metallic borophene nanosheets. Nat. Commun. 16, 5739 (2025).
Zhang, Z. et al. Few-layer borophene prepared by mechanical resonance and its application in terahertz shielding. ACS Appl. Mater. Interfaces 12, 19746–19754 (2020).
Huang, C. et al. Continuous MXene fibers with near-gigapascal tensile strength via radial confinement and axial stretching. Nat. Commun. 17, 1277 (2026).
